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SODIUM BICARBONATE Safety Data Sheet - Syndel - sodium bicarbonate formula

SODIUM BICARBONATE Safety Data Sheet - Syndel-sodium bicarbonate formula

Safety Data Sheet
Section 1: Identification
Product Name: SODIUM BICARBONATE Emergency Phone Number: CHEMTREC: 800-424-9300
Other Identification: Baking Soda, Bicarbonate of Soda, CAS#: 144-55-8
Sodium Hydrogen Carbonate
Manufacturer: Natural Soda LLC Intended Use: food and baking ingredient, specialty products,
3200 County Road 31 fire retardant, animal nutrition, pharmaceutical, household and
Rifle, Colorado 81650 USA personal care, mild cleaners, general industrial.
Phone Number: 1-970-878-3674
Section 2: Hazard(s) Identification
Classification of Substance Other Hazards
Classification (GHS-US): Not Classified Inhalation: Breathing dusts may cause coughing or difficulty
Label Elements breathing.
GHS-US Labeling: No applicable labeling Eye Contact: Direct eye contact may cause irritation, reddening
Unknown Acute Toxicity (GHS-US) or tearing.
Not available Skin Contact: Direct contact may cause irritation.
Section 3: Composition / Information on Ingredients
Substance CAS#: 144-55-8
Common Name: Sodium Bicarbonate Formula: NaHCO3
Chemical Names: Sodium Bicarbonate, Bicarbonate of Soda Purity: 99+% (w/w)
Sodium Hydrogen Carbonate Impurities: No impurities relevant for classification and labeling.
Section 4: First-aid Measures
Most Important Symptoms and Effects, Acute and Delayed Description of First-Aid Measures
General: None expected under normal conditions of use. General: No known delayed effects. Never give anything by
mouth to an unconscious person. If you feel unwell, seek
medical advice.
Eye Contact: Contact may cause irritation due to mechanical Eye Contact: Immediately rinse eyes with water. Remove any
abrasion. contact lenses, and continue flushing eyes with running water for
at least 15 minutes. Get immediate medical attention.
Skin: Contact with large amounts of dust may cause mechanical Skin: Wash affected areas with plenty of water, and soap if
irritation. available, for several minutes. Seek medical attention if irritation
develops or persists.
Inhalation: Prolonged inhalation of dust may cause respiratori Inhalation: Remove from area to fresh air. Seek medical
irritation. attention if respiratory irritation develops or if breathing becomes
Ingestion: Large doses may product systemic alkalosis and Ingestion: May cause nausea, vomiting and abdominal pain.
expansion in extracellular fluid volume with edema. Large doses can cause alkalosis.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention.
Section 5: Fire-fighting Measures
General: This product will not burn, and can be used a dry powder extinguishing medium.
Extinguishing Media Advice for Firefighters
Suitable Extinguishing Media: Use material suitable for No special precautions required.
surrounding fire conditions. General Measures: Wear self-contained breathing apparatus
Unsuitable Extinguishing Media: none. when entering area unless atmosphere is proved to be safe.
Special Hazards Arising from the Substance Protection During Firefighting: Do not enter fire area without
Fire Hazard: Not Flammable proper protective equipment, including respiratory protection.
Explosion Hazards: Not Explosive Hazardous Combustion Products: CO2 (displacement of
Reactivity: Hazardous reactions will not occur under normal breathable atmosphere).
Section 6: Accidental Release Measures
General Personal Precautions, Protective Equipment and Emergency Procedures: For dry spills, sweep or shovel and place in
containers for disposal in accordance with applicable regulations (see Disposal Considerations section). Handle in accordance with
good industrial hygiene and safety practice. Avoid formation of dust. Avoid excess skin and eye contact. Avoid contamination of bodies
of water during cleanup.
For Non-Emergency Personnel Environmental Precautions
Keep dust levels to a minimum Avoid any mixture with an acid into sewer or drain (CO2 gas
Wear suitable personal protective equipment formation)
For Emergency Personnel Methods for Containment: vacuum or shovel into bags
Equip cleanup crew with proper protection. Methods for Cleanup: Avoid generation of dust during cleanup
Ventilate area.. of spills. Keep in suitable closed labeled container for disposal.
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Safety Data Sheet
Section 7: Handling and Storage
Precautions for Safe Handling Conditions for Safe Storage
General: Avoid contact with eyes, skin and clothing. Wash hands General: Store in a cool, dry and well-ventilated location. Good
thoroughly with soap and water after handling and before eating, housekeeping should be maintained to minimize dust
drinking or smoking. accumulation and generation.
Incompatibilities: Keep away from acids, water.
Section 8: Exposure Controls / Personal Protection
Control Parameters (Particles not otherwise classified) Eye Protection: Use vented goggles or safety glasses in
US ACGIH (TWA) : 3 mg/m3 Respirable Dust excessively dusty conditions
10 mg/m3 Total Dust Skin Protection: Not required under normal conditions. Use
gloves and protective clothing if excessively dusty, or if skin is
US OSHA PEL (TWA): 5 mg/m3 Respirable Dust damaged
15 mg/m3 Total Dust Respiratory Protection: None required where adequate
ventilation is provided. If airborne concentrations are high, use a
Engineering Controls: Use local exhaust ventilation to keep NIOSH/MSHA approved respirator that has been selected by a
airborne levels below exposure limits. technically qualified person for the specific work conditions.
Section 9: Physical and Chemical Properties
Solubility In Water: 8.8% at 20?C pH Value: 1% Solution = 8.0-8.5
Appearance: White granular solid Flash Point: Not Applicable
Molecular Weight: 84.01 Specific Gravity: (H2O=1 @ 4?C): 2.16
Boiling Point: Decomposes on heating Bulk Density: 60 lbs/ ft3
Melting Point: Decomposes above 500C without melting Vapor Pressure: Not Applicable
Section 10: Stability and Reactivity
Reactivity: Hazardous reactions will not occur under normal Conditions to Avoid: Exposure to moisture or moist air.
circumstances. Temperatures above 150oF (65oC)
Chemical Stability: Stable in dry air, in moist air forms sodium Incompatible Materials: Acids. Aluminum (tarnishes).
carbonate, an irritant.
Possibility of Hazardous Reactions: Hazardous polymerization Hazardous Decomposition Products: When heated to
will not occur. decomposition, sodium bicarbonate produces carbon dioxide.
Section 11: Toxicological Information
Symptoms after Inhalation: Prolonged inhalation of dust may
EYES: Mid (rabbit) 100 mg/ 30 sec cause respiratory irritation.
SKIN: Mid (human) 30 mg/ 3 days-intermittent Symptoms after Skin Contact: Large amounts of dust may
INGESTION: Oral LD60 (rat) 4220 mg/kg cause mechanical irritation.
Oral LD60 (mouse) 3360 mg/kg Symptoms after Eye Contact: Contact may cause irritation due
Oral LDL5 (man) 20 mg/kg/ 5 days-intermittent to mechanical abrasion.
Oral LDL5 (infant) 1260 mg/kg Symptoms after Ingestion: Large doses may produce
symptomatic alkalosis and expansion in extracellular fluid volume
with edema.
Chronic Symptoms: None expected under normal conditions of
Skin Corrosion/Irritation: Not classified
Serious Eye Damage/Irritation: Not classified CARCINOGENICITY: Sodium Bicarbonate is not listed as a
Respiratory or skin sensitization: Not classified carcinogen by the Environmental Protection Agency (EPA), the
Germ cell mutagenicity: Not classified State of California, the National Toxicology Program, or the
Teratogenicity: Not classified International Agency for Research on Cancer. See Regulatory
Carcinogenicity: Not classified Information Section for additional information.
Specific Target Organ Toxicity: Not classified
Reproductive Toxicity: Not classified
Aspiration Hazard: Not classified
Section 12: Ecological Information
LC 50 Fish 1: 7100 mg/l (Bluegill) Persistence and Degradability: Not established
LC 50 Fish 1: 8250-9000 mg/l (Exposure time 96h) Bioaccumulative Potential: Not established
EC 50 Daphnia 1: 4100 mg/l Mobility in Soil: Not available
EC 50 Daphnia 1: 2350 mg/l (Exposure time 48h) Other Adverse Effects: No other adverse effects are identified
LC 50 Fish 2: 7700 mg/l (Rainbow trout)
Section 13: Disposal Considerations
Disposal Guidance: If permitted by local and state regulations, place in a hazardous or industrial waste landfill. Tonnage quantities are
not, however, recommended for the landfill, and if possible, should be re-used for an appropriate application. Small quantities may be
flushed to sewers if permitted by NPDES or POTW permit. Refer to federal, state, provincial and local regulations for applicable site-
specific requirements. Keep out of drinking water sources. See Regulatory Information for more details.
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Safety Data Sheet
Section 14: Transport Information
U.S. Department of Transportation (DOT) Identification Number: Sodium Bicarbonate is not a DOT Hazardous Material.
International Transportation: Sodium Bicarbonate has no U.N. number, and is not regulated under international rail, highway, water, or
air transport regulations.
Transportation of Dangerous Goods (TDG): Not Regulated.
Section 15: Regulatory Information
TSCA Number: 144-55-8 California Proposition 65: Not listed.
RCRA (40 CFR 261): Not listed under any section. SARA III: Section 302-No:311-Yes: 312-Yes: 313-No
CERCLA (Superfund): Not listed under any section. Workplace Hazardous Materials Information System
(WHMIS): Not a controlled product.
Clean Water Act (CWA): Not listed. EU CLASSIFICATION: Not a dangerous substance.
Safe Drinking Water Act (SWDA): Not listed. OSHA: Treat as particulates not otherwise regulated.
International Agency for Research on Cancer: Not listed. ACGIH: Treat as particulates not otherwise regulated.
NTP Annual Report on Carcinogens: Federal Drug Agency (FDA): Sodium bicarbonate is permitted
OSHA Carcinogen: Not listed. for the following uses: Antibiotic manufacturing; cake, pancake
CONEG Model Legislation: Not listed. and ready-mixes; catalyst manufacture; chemical; dentifrices;
explosives; fire extinguishers; food colors; food conditioner;
papermaking; pharmaceuticals; photography; self-rising flour;
starches; sugar refining; textiles.
International Listings
AICS (Australian Inventory of Chemical Substances.
Canadian DSL (Domestic Substances List).
IECSC (Inventory of Existing Chemical Substances Produced or Imported in China).
EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Japanese ENCS (Existing & New chemical Substances) inventory
Korean ECL (Existing Chemicals List)
NZIoC (New Zealand Inventory of Chemicals)
PICCS (Philippines Inventory of Chemicals and Chemical Substances)
United States TSCA (Toxic Substances Control Act) inventory
Judgments as to the suitability of information herein for purchaser's purposes are necessarily purchaser's responsibility.
Therefore, although reasonable care has been taken in the preparation of such information, Natural Soda LLC extends no
warranties, makes no representation, and assumes no responsibility as to the accuracy or suitability of such information for
application to purchaser's intended purposes for consequences of its use.
American Conference of Governmental Industrial Hygienists (ACGIH). 1986. Documentation of threshold limit values and biological
exposure indices. 5thed. Cincinnati, OH. American Conference of Governmental Industrial Hygienists (ACGIH). 1990. 1990-1991
Threshold limit values for chemical substances and physical agents and biological exposure indices. Cincinnati, OH.
Budavari, S., M. J. O'Neil, A. Smith, and P. E. Heckelman, eds. 1989. The Merck Index. 11thed. Rahway, NJ: Merck & Co., Inc.
Clayton, G. D., and F. E. Clayton, eds. 1981. Patty's Industrial Hygiene and Toxicology. 3rded. New York: Wiley & Sons.
Department of Transportation (DOT). 1990. 49 S172.102. October 1.
Department of Transportation (DOT). 1991. 46 S150.105. August 23.
International Agency for Research on Cancer (IARC). 1987. IARC monographs on the evaluation of the carcinogenic risk of chemicals to
humans. Supplement 7, Overall evaluation of carcinogenicity: An updating of IARC monographs 1 to 42. Lyon, France: World Health
National Library of Medicine (NLM). 1991a. Hazardous substances databank. Bethesda, MD.
National Library of Medicine (NLM). National Institute for Occupational Safety and Health (NIOSH). Department of Health and Human
Services.1991b. Registry of toxic effects of chemical substances (RTECS).
National Toxicology Program (NTP). Division of Toxicology Research and Testing. 1991. Chemical Status report. Research Triangle
Park, NC. July.
Occupational Safety and Health Administration (OSHA). 1990. 29 S1910.1000. July 1.
Sax, N. I., and R. J. Lewis, Sr., eds. 1989. Dangerous properties of Industrial Materials. 7thed. New York: Van Nostrand Reinhold.
Registry of Toxic Effects of Chemical Substances Accession Number: VZ0950000.
Section 16: Other Information, including date of preparation or last revision
This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard
29 CFR 1910.1200.
Revision Date: 04/10/2015 Prepared by: Natural Soda LLC
Review Date: 11/24/2017 3200 County Road 31
Rifle, Colorado 81650
Ph: 970-878-3674
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Is sodium bicarbonate and bicarbonate of soda the same thing?They aren't all interchangeable! - by that's life! In short, bicarbonate of soda, sodium bicarbonate, bicarb soda and baking soda are different names for the same thing. In Australia and the UK it’s called bicarbonate of soda, but in the US it’s known as baking soda.